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Station 1: Dry Ice Experiments

Station 2: Methane Bubbles

Station 3: Liquid Nitrogen

Station 4: Metals, Alloys, Densities

Station 5: Polar vs. Non-Polar Substances

Station 3: Liquid Nitrogen

1.   FREEZE FLOWERS, TENNIS BALLS, RUBBER HOSE

What happens to flowers when immersed in liquid nitrogen?  Have students do this.  What do you hear when the flowers are immersed in the liquid nitrogen?  What does it sound like?  Is the liquid nitrogen boiling? 

What about a racquet ball?  Show how bouncy the racquet ball is and then put it in the liquid nitrogen.  Leave it in liquid nitrogen until the end of their time at this station.   

What about a Rubber hose?   Show how stretchy it is.  Put part of the hose in liquid nitrogen.  What are the changes in properties?  Have students stretch the frozen hose.

                                  

 

      Mention the space shuttle application.

 What is liquid nitrogen?  How cold is it?

     Temperature at which water boils?               100 oC         

     Temperature at which water freezes?               0 oC         

     Temperature of liquid nitrogen?                   -197 oC -->  very cold!

What is the fog above the liquid nitrogen?  Condensed water vapor.

     Put some liquid nitrogen in a tea kettle.  Have the students look inside the kettle and see the bubbling liquid.  Is the liquid nitrogen boiling?  Close the lid and hear the kettle whistle.  Don’t we need heat to boil liquid nitrogen?  Are we providing heat?  Where does the liquid nitrogen get the heat?  It absorbs heat from the kettle and from the air around the kettle.  Even from water molecules in the air.  See the water condensing on the kettle?  When we take heat from gaseous water molecules, they condense to form droplets of water

2.   SHRINK A BALLOON SHAPED LIKE A DOG, AND MAKE IT COME BACK TO LIFE

 

            Show them a balloon filled with air:  How does the balloon stay blown up?  Atoms and molecules move, collide with the walls of the balloon,  cause pressure inside the balloon. 

 

What happens when we put a balloon filled with air in the hot sun?  Why?

            Atoms and molecules speed up, increasing the number of collisions with the walls, increasing pressure.

What happens when we put a balloon filled with air in liquid nitrogen?  Why?  Put balloon in liquid nitrogen.  Have students do this also.

            Shrinks => molecules slow down

How does a microwave heat food?

Water molecules absorb radiation.  This causes the water molecules to rotate more. The rotating water molecules collide with other molecules in food, this increases the motion of molecules in food (it increases the energy, which makes the food hot.  Temperature is directly proportional to average kinetic energy.  When the temperature of a given substance is high, the kinetic energy of the atoms and molecules of which the substance is made is also high.

3.  WHO WANTS TO CONDENSE THEIR BREATH?  MAKE IT INTO A LIQUID AND SOLID

Blow up a balloon with air (5-6 inches in diameter, not bigger!) and put it on a test tube.

        What is in the air that you blew into the balloon?

                       N2, O2, CO2, H2O and whatever else is in the air you breathe out.

        What is in between the gas molecules in air?

                       Nothing - it is just empty space.

        How much space is between the molecules in a gas?  Do an experiment to show this.

      Immerse the test tube with the balloon on top in liquid nitrogen.

      What will happen?

      As the gas cools, the molecules slow down.   The volume of the balloon decreases and eventually completely deflates.

     This takes a little while so do the next activity and come back to this later.

      Remove the test tube from the liquid nitrogen.

      What is inside the test tube?    liquid  and  solid

      What liquids?          N2(l), O2 (l),

      What solids?           CO2 (s), H2O (s)

      How much space is between the liquid and solid molecules?

            Not much - they are in direct contact with each other.

      How does the volume of liquid and solid in the test tube compare with the volume of gas in the balloon?

            The volume of liquid/solid inside the test tube is much smaller than the volume of gas in the balloon. Thus, there is lots of space between the molecules in the gas.      

4.     CAN WE BLOW UP A BALLOON USING LIQUID NITROGEN?

At room temperature and pressure nitrogen is a gas.  Put ~ 200-300 mL of liquid nitrogen in a plastic water bottle using a funnel.  Put a balloon over the top and secure balloon.  What is happening?

In one bottle, put in ~200-300 mL water.  Put a balloon on top.  What is happening?

In another bottle put some chunks of dry ice.  Put a balloon on top.  What is happening?

water --->  stays in the liquid phase ---> balloon does not inflate

liquid nitrogen   --->  nitrogen gas  --->  blows up balloon fast

 dry ice (solid) --->  carbon dioxide gas --->  blows up balloon slowly

                 Ask students How can we speed this up?

      Liquid nitrogen absorbs heat from the container and the surrounding air molecules outside the container to form the nitrogen gas.  Energy is required to pull the N2 molecules apart.  It blows up the balloon, so energy in the form of heat is converted to energy in the form of work.

                                                 heat   --->  work

      Go back and finish the third activity – what happened to your breath inside the balloon? 

5.   Break the racquet ball. 

     Use tongs to take the very cold racquet ball out of the liquid nitrogen.  Hold the racquet ball at about your eye level and drop it.  It shatters.  Students can each take a piece of the ball to keep.  CAUTION:  the pieces of the ball are very cold.

      SAFETY:  Drop the frozen racquet ball -- throwing it with too much force can cause pieces to fly up and hurt someone.