former
graduate students
former undergraduate
researchers
former postdocs and
visiting scholars
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R. Daniel
Little little@chem.ucsb.edu
B.S.,
chemistry and mathematics, University of Wisconsin at Superior
Ph.D.
University of Wisconsin
Postdoctoral fellow, Yale University
A.P. Sloan Fellow
UCSB Plous Award recipient
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Graduate
Researchers
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Jennifer Mallory jmallory@chem.ucsb.edu
B.S. Chemistry, Cal Poly San Luis Obispo
My current
research efforts focus on trying to enhance the diastereoselectivity of
the electroreductive cyclization reaction (ERC). The use of
sacrificial anodes and metal additives is also being explored. In
addition, chiral auxiliaries are under investigation to control
absolute stereochemistry. The results will be showcased in the
synthesis of a natural product by using the ERC reaction to construct a
bond in the key step of the synthesis.
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Elizabeth
Flynn eflynnn@chem.ucsb.edu
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Abdul Hackim
ahackim@chem.ucsb.edu
B.S. Oregon
State University
The focus of my
research is upon the synthesis of simplified structural analogues of
the pseudopterosins. The goal of this project is to gain a better
understanding of their structure activity relationship profile.
I am also working on the total synthesis of (-)-diplopyrone and am
studying the role of stereoelectronic effects upon redox properties of
organic substrates. This work requires the development of
expertise in synthesis, electrochemistry, and the use of various
quantum calculation tools.
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Jinnie Myung jmyung@chem.ucsb.edu
B.S. Binghamton University-SUNY
My current
research focuses upon the generation and use of alkylidene
carbenes and their intramolecular addition to a pendant alkene, leading
to the formation of TMM diyls under very mild conditions.
Subsequent and sequential intramolecular cycloaddition has been shown
to lead cleanly to several different ring systems, including the
linearly fused tricyclopentanoid skeleton that
is common to a host of bioactive natural products.
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Randi
Gbur University
of Texas at Arlington
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Seung
Joon Yoo (Joon) UCSB
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Undergraduate
Researchers
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Ian Pahk
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Ian Pahk
At the
present time I am synthesizing several housanes, that is, moleculas
possessing the bicyclo[2.1.0] core framework. Some of these
systems display broad, ill-defined cyclic voltammograms. A series
of variable temperature CV experiments will be carried out in an effort
to determine the origin of the featureless curves. We susp[ect
that they are associated with the existence of dynamic influences that
we hope to "freeze out" as the temperature is lowered. This
research promises to provide insight into the role of stereoelectronic
effects in determining the ease of oxidation or reduction of a
substrate.
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Joaquin Gutierrez
- from UNAM in Mexico City
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Postdoctoral Scholar

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Dr. Wei Zhong
postdoctoral scholar to join the group
October 1,
2007; University of Georgia - Complex Carbohydrate
Research Institute
Dr. Zhong's research focuses primarily upon the chemistry and
pharmacology of the pseudopterosin class of marine natural
products. The research combines natural product characterization,
synthesis, degradation, total synthesis, as well as a detailed
investigation into what makes these molecules work.
Another area of investigation focuses upon a total synthesis of the
anti-tumor agent, aphidicolin. The synthetic approach is to
captilize upon sequential intramolecular diyl trapping and Diels-Alder
reactions.
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